When you say sticking, does it also look at times to try to climb up as it goes around either sprocket? This, because I had that some time ago and when I aligned my chain and also jack shaft chain it stopped. The rear wheel for safety I know should be as far back as it can go in the drop outs. I have a belt drive which goes to the back wheel sheave that is not as critical as a chain. I still want to keep it from hitting the frame which is close by and also have it not put no sideways force on the pulleys, so I do not have the two side of the axle in the drop out exactly even. If I didn't have slight wide knobby tire on rear wheel it would be a straight line. Noticing this while riding, I can't tell at all. The are some threads on MB that mention of things built to act as guides to check alignment. I did by eye without and just kept spinning wheel in forward direction and kept seeing if jumping tried to happen. After some adjustment no rubbing. A dual jack shaft system using chains jumping tried to happen also and alignment there was done with the mounts I made for the pillow bearing holders. Some pillow bearings have movement free in any direction and self align, I did not buy those ball joint type of pillow bearings so I must check alignment any time I change a sprocket size to change the gear ratio. Important also is I remove sections of chain or a time the whole chain when with the chain remove I check the links to see if they bent both directions freely after clean and lube. Some were sticking and I could tell they were bent. Trying to fix by using a needle nose pliers and screw driver must sound dumb, but mostly it was to find out if my theory was correct that they were actually bent. Then I removed that section of chain. Holding the chain over a stick and pulling it while it made a very tight radius bend and not kinking at all, I deduced then the chain was probably OK. Then if it tried to climb a sprocket and jump, I just looked at the alignment and tension. Also checking the chain again if things did not work out as just testing trying to align just might be damaging the chain if it tried to jump. The sprocket being defective not true from manufacturer and or damage from chain trying to jump also taken into consideration.
MT