I occasionally clean the pulley with acetone and clean cloth. Gotta keep grease off the pulley. The belt of course has to be out of the way as acetone is not good for the belt.
The wider belt is what is used on most torque converters, but for your use, and as my bike too, both pulleys would have to be changed. The one on the rear wheel I've not seen in larger width. The frames rear stays would have to be able to clear the pulley and the line up of the belt still be good.
It would seem with what ever that fast speed is, you have a lower ratio than my bike. If I got 19 mph as GPS at 20:1 ratio, I know I was over reving to may 5000 rpm where it should be 3500 max at I guess about 12 mph. I have the 20:1 as I ride dirt trails exclusively since I got a DMV OHV Reg.
I can remember when it was at 8:1 ratio and it slipped not the belt, but the centrifugal belt clutch. Not the belt on the clutch, but probably the shoes on the bell.
It was insanely too high a ratio. 17:1 ratio did get the 26 inch wheel to get a bit more speed, but it required run up to climb hills. Then at 20:1 ratio slipping started with a belt I do not have currently enough adjustment to get a cogged belt to fit.
I will probably see about a chain for my first reduction which I think I can still have the same ratio by reconfiguring other sprocket that connect two jack shaft I am running.
MT
See Picture with Gates Tripower Belt (cogged) shown in 4th of 5 pictures in post 167 on page 17 of my thread "Art Fish Mobile Motor Bike prior Motor Bike DIY'er build to add side car maybe?"
The first picture shows the Gates Powerated regular belt which I swapped out.
http://motorbicycling.com/showthread.php?p=554269&highlight=gates#post554269